This resource offers a detailed review of the events that led South Carolina to nullify the Tariffs of 1828 and 1832, as well as to pass the Nullification Ordinance, which questioned the federal government's authority to enforce any law...

Here is a nice set of worksheets to get you started on teaching your young historians about the "Corrupt Bargain" in the presidential election of 1824, as well as the Tariff of 1828 and the emergence of new political parties.